Oxidations of benzyl alcohol by hydrogen peroxide in the presence of complexed peroxoniobium(v) species

被引：23

作者：

Batista, CMD

Melo, SCD

Gelbard, G

Lachter, ER

机构：

[1] UNIV FED RIO DE JANEIRO, INST QUIM, DEPT QUIM ORGAN, LAB CATALISE ORGAN, BR-21949900 RIO DE JANEIRO, BRAZIL

[2] INST RECH CATALYSE, CNRS, F-69626 VILLEURBANNE, FRANCE

来源：

JOURNAL OF CHEMICAL RESEARCH | 1997年 / 03期

关键词：

D O I：

10.1039/a605944i

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The influence of ligands around peroxo niobium complexes and of the ratio of oxygen-source substrates towards the efficiency of the niobium(v)-catalysed oxidation of benzyl alcohol to benzaldehyde by hydrogen peroxide has been analysed: the use of ligands such as phenylphosphonic acid and 2,2'-bipyridyl associated with peroxoniobate gave efficient systems.

引用

页码：92 / 93

页数：2

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