Coupled infrared extinction spectra and size distribution measurements for several non-clay components of mineral dust aerosol (quartz, calcite, and dolomite)

Simultaneous size distributions and Fourier transform infrared (FTIR) extinction Spectra have been measured for several representative components of mineral dust aerosol (quartz, calcite, and dolomite) in the fine particle size mode (D = 0.1 -1 mu m). Optical constants drawn from the published literature have been used in combination with the experimentally determined size distributions to Simulate the extinction spectra. In general, Mie theory does not accurately reproduce the peak position or band shape for (lie prominent IR resonance features in the 800-1600 cm(-1) spectral range. The resonance peaks in the Mie simulation are consistently blue shifted relative to the experimental spectra by similar to 20-50cm(-1). Spectral simulations, derived front a simple Rayleigh-based analytic theory for a "continuous distribution of ellipsoids" particle shape model, better reproduce the experimental spectra, despite the fact that the Rayleigh approximation is not strictly satisfied in these expriments. These results differ from our previous studies of particle shape effects in silicate clay mineral dust aerosols where a disk-shaped model for the particles was found to be more appropriate. (C) 2008 Elsevier Ltd. All rights reserved.