Structure and physical properties of molecular metals based on BED-TTF

被引：6

作者：

Horiuchi, S ^{[1
]}

Yamochi, H ^{[1
]}

Saito, G ^{[1
]}

Matsumoto, K ^{[1
]}

机构：

[1] KYOTO UNIV,GRAD SCH HUMAN & ENVIRONM STUDIES,SAKYO KU,KYOTO 60601,JAPAN

来源：

SYNTHETIC METALS | 1997年 / 86卷 / 1-3期

关键词：

electrocrystallization; conductivity; X-ray diffraction; magnetic measurements;

D O I：

10.1016/S0379-6779(97)80914-9

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Preparation, characterization, and physical properties of several metallic bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) complexes are presented. The direct reaction with chloranilic acid (H(2)CHA) gave 2:1 complex, the crystal structure of which consists of two-dimensional (2D) donor layer and 1D stack of deprotonated acceptor molecules. The electrocrystallization of the donor in the presence of MnBr42- and water yielded a novel salt with four components, (BEDO-TTF)(2)Br[MnBr2(H2O)4] (H2O), which contains 2D donor layers and localized magnetic moments (S = 5/2).

引用

页码：1809 / 1810

页数：2

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