Exploiting modularity in template-controlled synthesis: a new linear template to direct reactivity within discrete hydrogen-bonded molecular assemblies in the solid state

被引：89

作者：

Papaefstathiou, GS ^{[1
]}

Kipp, AJ ^{[1
]}

MacGillivray, LR ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

CHEMICAL COMMUNICATIONS | 2001年 / 23期

关键词：

D O I：

10.1039/b106584j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co-crystallization of 1,8-naphthalenedicarboxylic acid (1,8-nap) with trans-1,2-bis(n-pyridyl) ethylene (n,n'-bpe) (n=2 or 4) yields a discrete four-component molecular assembly, 2(n,n'-bpe).2(1,8-nap) 1, that is held together by four O-H . . .N hydrogen bonds where the dicarboxylic acid, serving as a linear template, directs alignment of olefins in the solid state for [2+2] photoreaction.

引用

页码：2462 / 2463

页数：2

共 23 条

[1]

Anastas P. T., 1998, GREEN CHEM THEORY PR

[2]

Anderson S., 1999, TEMPLATED ORGANIC SY, P38, DOI 10.1002/9783527613526.ch01

[3] Nanostructured polymer duplexes via the covalent casting of 1-dimensional H-bonding motifs: A new strategy for the self-assembly of macromolecular precursors [J].