Emulsion polymerization of n-butyl methacrylate by reverse atom transfer radical polymerization

被引：175

作者：

Qiu, J ^{[1
]}

Gaynor, SG ^{[1
]}

Matyjaszewski, K ^{[1
]}

机构：

[1] Carnegie Mellon Univ, Dept Chem, Ctr Macromol Engn, Pittsburgh, PA 15213 USA

来源：

MACROMOLECULES | 1999年 / 32卷 / 09期

关键词：

D O I：

10.1021/ma981695f

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The controlled/'living" radical polymerization of n-butyl methacrylate was conducted in an emulsion under reverse atom transfer radical polymerization (ATRP) conditions. The initiators used were conventional water-soluble initiators, such as potassium persulfate (KPS), 2,2'-azobis(2-methylpropionamidine) dihydrochloride (V-50), and 2,2'-azobis[2-(2-dimidazolin-2-yl)propane] dihydrochloride (VA-044). The transition metal catalyst employed was copper(II) dibromide with 4,4'-dialkyl-2,2'-bipyridine as the ligands.

引用

页码：2872 / 2875

页数：4

共 25 条

[1]

Behrman E. J., 1980, Reviews in Inorganic Chemistry, V2, P179

[2] Controlled radical polymerization in emulsion [J].

Bon, SAF ;

Bosveld, M ;

Klumperman, B ;

German, AL .

MACROMOLECULES, 1997, 30 (02) :324-326

[3] Living free-radical polymerization by reversible addition-fragmentation chain transfer: The RAFT process [J].

Chiefari, J ;

Chong, YK ;

Ercole, F ;

Krstina, J ;

Jeffery, J ;

Le, TPT ;

Mayadunne, RTA ;

Meijs, GF ;

Moad, CL ;

Moad, G ;

Rizzardo, E ;

Thang, SH .

MACROMOLECULES, 1998, 31 (16) :5559-5562

[4] Mechanisms and kinetics of nitroxide-controlled free radical polymerization [J].

Fukuda, T ;

Terauchi, T ;

Goto, A ;

Ohno, K ;

Tsujii, Y ;

Miyamoto, T ;

Kobatake, S ;

Yamada, B .

MACROMOLECULES, 1996, 29 (20) :6393-6398

[5] CONTROLLED RADICAL POLYMERIZATION BY DEGENERATIVE TRANSFER - EFFECT OF THE STRUCTURE OF THE TRANSFER AGENT [J].

GAYNOR, SG ;

WANG, JS ;

MATYJASZEWSKI, K .

MACROMOLECULES, 1995, 28 (24) :8051-8056

[6] Controlled/"living" radical polymerization applied to water-borne systems [J].

Gaynor, SG ;

Qiu, J ;

Matyjaszewski, K .

MACROMOLECULES, 1998, 31 (17) :5951-5954

[7] NARROW MOLECULAR-WEIGHT RESINS BY A FREE-RADICAL POLYMERIZATION PROCESS [J].

GEORGES, MK ;

VEREGIN, RPN ;

KAZMAIER, PM ;

HAMER, GK .

MACROMOLECULES, 1993, 26 (11) :2987-2988

[8]

Gilbert R. G., 1995, Emulsion Polymerization: A Mechanistic Approach

[9]

Greszta D, 1997, J POLYM SCI POL CHEM, V35, P1857

[10] Well-defined random copolymers by a ''living'' free-radical polymerization process [J].

Hawker, CJ ;

Elce, E ;

Dao, JL ;

Volksen, W ;

Russell, TP ;

Barclay, GG .

MACROMOLECULES, 1996, 29 (07) :2686-2688

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