One-step flame synthesis of an active Pt/TiO2 catalyst for SO2 oxidation -: A possible alternative to traditional methods for parallel screening

被引:57
作者
Johannessen, T [1 ]
Koutsopoulos, S
机构
[1] Tech Univ Denmark, Dept Chem Engn, DK-2800 Lyngby, Denmark
[2] Tech Univ Denmark, Interdisciplinary Res Ctr Catalysis, ICAT, DK-2800 Lyngby, Denmark
[3] Tech Univ Denmark, Dept Chem, DK-2800 Lyngby, Denmark
关键词
platinum; titania; catalyst; flame synthesis; one-step; oxidation; screening;
D O I
10.1006/jcat.2001.3447
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Flame synthesis as a route for production of composite metal oxides has been employed for the one-step synthesis of a supported noble metal catalyst, i.e., a Pt/TiO2 catalyst, by simultaneous combustion of Ti-isopropoxide and platinum acetylacetonate in a quench-cooled flame reactor. The average size of the platinum particles supported on aggregated nanoparticles of TiO2 is approximately 2 nm. The high SO2 oxidation activity of the catalyst proves that platinum is not "hidden" in the titania matrix. The flame-produced catalyst showed catalytic activity similar to that of samples prepared by wet platinum impregnation of pure titania. (C) 2002 Elsevier Science.
引用
收藏
页码:404 / 408
页数:5
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