Heterosupramolecular chemistry: Self-assembly of an electron donor (TiO2 nanocrystallite)-acceptor (viologen) complex

被引：37

作者：

Cusack, L ^{[1
]}

Marguerettaz, X ^{[1
]}

Rao, SN ^{[1
]}

Wenger, J ^{[1
]}

Fitzmaurice, D ^{[1
]}

机构：

[1] NATL UNIV IRELAND UNIV COLL DUBLIN,DEPT CHEM,DUBLIN 4,IRELAND

来源：

CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 08期

关键词：

D O I：

10.1021/cm9605173

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A TiO2 nanocrystallite has been modified to selectively bind, by complementary hydrogen bonding, a uracil substrate incorporating a viologen moiety. Bandgap excitation of the self-assembled donor (TiO2 nanocrystallite)-acceptor (viologen) complex results in electron transfer. Some implications of these findings for the self-assembly of functional nanostructures containing both condensed phase and molecular components are considered.

引用

页码：1765 / 1772

页数：8

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