Modulated structure of Rb2ZnCl4 in the soliton regime close to the lock-in phase transition -: art. no. 014112

The structure of the incommensurate phase of Rb2ZnCl4 has been determined at 194 K (2 K above the lock-in transition) within the soliton regime using satellites up to fifth order. The rather anharmonic modulation functions agree with the expected steplike functions supported by theoretical arguments. In addition, the constancy of the ratio between the amplitudes of the fifth-order and first-order harmonics, a relation predicted by theory, indicate the correctness of the model and imply a value of 0.4 for the soliton density n(s). A symmetry mode analysis shows that the incommensurate structure is consistent with the one of the lock-in phase in the sense that the displacement pattern of every symmetry mode remains unaltered in the transition except for a global change in the amplitudes.