Mathematical modelling of self-sustained isothermal oscillations in N2O decomposition on Cu-ZSM5

被引：16

作者：

Ciambelli, P

Di Benedetto, A

Pirone, R

Russo, G

机构：

[1] CNR, Ist Ric Combust, I-80125 Naples, Italy

[2] Univ Naples Federico II, Dipartimento Ingn Chim, Naples, Italy

[3] Univ Salerno, Dipartimento Ingn Chim & Alimentare, I-84084 Fisciano, SA, Italy

来源：

CHEMICAL ENGINEERING SCIENCE | 1999年 / 54卷 / 13-14期

关键词：

oscillations; N2O; decomposition; Cu-ZSM5; kinetic model; catalysis;

D O I：

10.1016/S0009-2509(98)00469-2

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

A kinetic model for self-sustained isothermal oscillations occurring during N2O decomposition on Cu-ZSM5 has been developed. The dynamic behaviour has been explained by a reaction mechanism producing periodic changes of the state of oxidation of the catalyst. The oscillations have been simulated by assuming that the solid-solid reaction step exhibits an activation energy proportional to the catalyst reduction degree. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2555 / 2559

页数：5

共 14 条

[1]

Belayaev V.D., 1977, P 6 INT C CAT, V2, P758

[2]

BELAYAEV VD, 1973, KINET KATAL, V14, P810

[3] Spontaneous isothermal oscillations in N2O decomposition over a Cu-ZSM5 catalyst [J].