Towards an ammonia-mediated hydrogen economy?

被引:404
作者
Christensen, CH
Johannessen, T
Sorensen, RZ
Norskov, JK
机构
[1] Tech Univ Denmark, Dept Chem, Ctr Sustainable & Green Chem, DK-2800 Lyngby, Denmark
[2] Tech Univ Denmark, Amminex AS, DK-2800 Lyngby, Denmark
[3] Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark
关键词
hydrogen; ammonia; desorption;
D O I
10.1016/j.cattod.2005.10.011
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Materialization of a hydrogen economy could provide a solution to significant global challenges, In particular. the possibility of improving the efficiency and simultaneously minimizing the environmental impact of energy conversion processes, together with the opportunity to reduce the dependency of fossil fuels, are main drivers for the currently increasing research and development efforts. However. significant technological breakthroughs are necessary for making a hydrogen economy feasible. In particular, it is necessary to develop appropriate hydrogen storage and transportation technologies. Recently, metal ammine salts were proposed as safe, reversible. high-density and low-cost hydrogen carriers. Here, we discuss how this development could provide a platform for using ammonia as a fuel for the hydrogen economy, We do that by comparing various possible hydrogen carriers with respect to energy and cost efficiency, infrastructure requirements, safety concerns and also environmental impact. Based on this, it appears that in several scenarios, the use of metal ammines offsets significant new opportunities. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:140 / 144
页数:5
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