FT-IR and FT-Raman spectroscopic investigations of adsorption of 2-aminopyridine on natural and ion-exchanged bentonites

被引：16

作者：

Akyüz, S

Akyüz, T

Davies, JED

机构：

[1] Istanbul Univ, Dept Phys, TR-34459 Istanbul, Turkey

[2] Cekmece Nucl Res & Training Ctr, Istanbul, Turkey

[3] Univ Lancaster, Div Environm Sci, Lancaster LA1 4YQ, England

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1999年 / 482卷

关键词：

FT-IR; FT-Raman; clay; bentonite; intercalation; aminopyridine;

D O I：

10.1016/S0022-2860(98)00634-6

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The adsorption of 2-aminopydine (2AP) on natural and ion-exchanged bentonites (Mn-, Fe-, Co- or Ni-bentonite) have been investigated using IR and Raman Spectroscopy. The intercalation of 2AP within natural and ion-exchanged bentonites has been shown by X-ray diffraction to increase the interlayer spacing. Vibrational spectroscopy indicates that intercalated 2AP molecules are coordinated to Lewis acid sites or exchangeable cations (directly or indirectly through water bridges). It is concluded that ring nitrogen, not the amino nitrogen is involved in coordination. Moreover amino group hydrogens are found to be involved in hydrogen bonding interaction with water molecules (NH ... OH2). (C) 1999 Elsevier Science B.V. All rights reserved.

引用

页码：49 / 52

页数：4

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