Synthesis of amino-sugars using the directed dihydroxylation reaction

被引：24

作者：

Donohoe, TJ ^{[1
]}

Blades, K ^{[1
]}

Helliwell, M ^{[1
]}

机构：

[1] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 17期

关键词：

D O I：

10.1039/a904991f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis of protected forms of two amino-sugars, talosamine 1 and allosamine 2, is described; the syn, syn stereochemistry at C-2, C-3 and C-4 was controlled by the use of a hydrogen-bonding directed dihydroxylation reaction using stoichiometric and catalytic OsO4; proof of the relative stereochemistry of the allosamine series was obtained through an X-ray crystal structure of a protected derivative.

引用

页码：1733 / 1734

页数：2

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