Shuttling through anion recognition

被引:155
作者
Keaveney, CM [1 ]
Leigh, DA [1 ]
机构
[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland
关键词
anions; hydrogen bonds; molecular recognition; molecular shuttles; rotaxanes;
D O I
10.1002/anie.200353248
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A negative response: Anion formation induces translocation of the macrocycle in a molecular shuttle (see picture). Shuttling only occurs in polar solvents and is unaffected by the nature of the countercation or the presence of other anions.
引用
收藏
页码:1222 / 1224
页数:3
相关论文
共 43 条
[2]   Electrochemically switchable hydrogen-bonded molecular shuttles [J].
Altieri, A ;
Gatti, FG ;
Kay, ER ;
Leigh, DA ;
Martel, D ;
Paolucci, F ;
Slawin, AMZ ;
Wong, JKY .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (28) :8644-8654
[3]   Remarkable positional discrimination in bistable light- and heat-switchable hydrogen-bonded molecular shuttles [J].
Altieri, A ;
Bottari, G ;
Dehez, F ;
Leigh, DA ;
Wong, JKY ;
Zerbetto, F .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2003, 42 (20) :2296-2300
[4]  
Altieri A., 2003, ANGEW CHEM, V115, P2398
[5]  
[Anonymous], 1997, SUPRAMOLECULAR CHEM
[6]   Acid-base controllable molecular shuttles [J].
Ashton, PR ;
Ballardini, R ;
Balzani, V ;
Baxter, I ;
Credi, A ;
Fyfe, MCT ;
Gandolfi, MT ;
Gómez-López, M ;
Martínez-Díaz, MV ;
Piersanti, A ;
Spencer, N ;
Stoddart, JF ;
Venturi, M ;
White, AJP ;
Williams, DJ .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :11932-11942
[7]  
Beer PD, 2001, ANGEW CHEM INT EDIT, V40, P486, DOI 10.1002/1521-3773(20010202)40:3<486::AID-ANIE486>3.3.CO
[8]  
2-G
[9]   A CHEMICALLY AND ELECTROCHEMICALLY SWITCHABLE MOLECULAR SHUTTLE [J].
BISSELL, RA ;
CORDOVA, E ;
KAIFER, AE ;
STODDART, JF .
NATURE, 1994, 369 (6476) :133-137
[10]   Amide based receptors for anions [J].
Bondy, CR ;
Loeb, SJ .
COORDINATION CHEMISTRY REVIEWS, 2003, 240 (1-2) :77-99