Indium-mediated reaction of 1,3-dichloro- and 1,3-dibromopropenes with carbonyl compounds, generation of novel 3,2-diindiopropene

被引:22
作者
Araki, S
Hirashita, T
Shimizu, H
Yamamura, H
Kawai, M
Butsugan, Y
机构
[1] Department of Applied Chemistry, Nagoya Institute of Technology, Nagoya 466, Gokiso-cho, Showa-ku
关键词
D O I
10.1016/0040-4039(96)01925-9
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Indium-mediated reaction of 1,3-dichloropropene with aldehyde gave syn-chlorohydrin predominantly. A similar reaction of 1,3-dibromopropene gave vinyloxirane and homoallyl alcohol; the former is formed from gamma-bromoallylindium via the corresponding bromohydrin, and the latter is considered to be derived from a unique allylic diindium reagent, 3,3-diindiopropene. Copyright (C) 1996 Elsevier Science Ltd
引用
收藏
页码:8417 / 8420
页数:4
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