Towards green routes for polymer synthesis: Polymerization of cyclodextrin host-guest complexed diethyl fumarate and copolymerization with complexed styrene in homogenous aqueous solution

被引：19

作者：

Choi, SW ^{[1
]}

Ritter, H ^{[1
]}

机构：

[1] Univ Dusseldorf, Inst Organ & Macromol Chem, D-40225 Dusseldorf, Germany

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 06期

关键词：

copolymerization; cyclodextrin; diethyl fumarate; homopolymerization; host-guest systems; styrene;

D O I：

10.1002/marc.200300181

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The radical homo- and copolymerization of styrene (1) and diethyl fumarate (DEF, 2) in the presence of methylated beta-cyclodextrin (beta-CD) in water is described. It has been shown for the first time that homopolymerization of CD-complexed DEF and its copolymerization with CD-complexed styrene occur readily in aqueous solution. In the absence of CD, or in organic solvents, the homopolymerization of DEF, is strongly retarded.

引用

页码：716 / 719

页数：4

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