Director field configurations around a spherical particle in a nematic liquid crystal

被引:191
作者
Stark, H [1 ]
机构
[1] Univ Stuttgart, Inst Theoret & Angew Phys, D-70550 Stuttgart, Germany
关键词
D O I
10.1007/s100510050860
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
We study the director field around a spherical particle immersed in a uniformly aligned nematic liquid crystal and assume that the molecules prefer a homeotropic orientation at the surface of the particle. Three structures are possible: a dipole, a Saturn-ring, and a surface-ring configuration, which we investigate by numerically minimizing the Frank free energy supplemented by a magnetic-field and a surface term. In the dipole configuration, which is the absolutely stable structure for micron-size particles and sufficiently strong surface anchoring, a twist transition is found and analyzed. We show that a transition from the dipole to the Saturn ring configuration is induced by either decreasing the particle size or by applying a magnetic field. The effect of metastability and the occurrence of hysteresis in connection with a magnetic field are discussed. The surface-ring configuration appears when the surface-anchoring strength W is reduced. It is also favored by a large saddle-splay constant K-24 A comparison with recent experiments [10,13] gives a lower bound for W, i.e., W > 0.06 erg/cm(2) for the interface of water and pentylcyanobiphenyl (5CB) in the presence of the surfactant sodium dodecyl sulfate.
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收藏
页码:311 / 321
页数:11
相关论文
共 42 条
[1]   FLUCTUATION-INDUCED LONG-RANGE FORCES IN LIQUID-CRYSTALS [J].
AJDARI, A ;
PELITI, L ;
PROST, J .
PHYSICAL REVIEW LETTERS, 1991, 66 (11) :1481-1484
[2]  
[Anonymous], 1994, CASIMIR EFFECT CRITI
[3]  
BAJC J, COMMUNICATION
[4]  
BERREMAN DW, 1984, PHYS REV A, V30, P1955, DOI 10.1103/PhysRevA.30.1955
[5]   EXPERIMENTAL STUDIES OF THE ANCHORING ENERGY OF NEMATIC LIQUID-CRYSTALS - INVITED LECTURE [J].
BLINOV, LM ;
KABAYENKOV, AY ;
SONIN, AA .
LIQUID CRYSTALS, 1989, 5 (02) :645-661
[6]   Forces in an inhomogeneously ordered nematic liquid crystal: Stable and metastable states [J].
Borstnik, A ;
Zumer, S .
PHYSICAL REVIEW E, 1997, 56 (03) :3021-3027
[7]  
BORSTNIK A, IN PRESS PHYS REV E
[8]   THEORY OF MAGNETIC SUSPENSIONS IN LIQUID CRYSTALS [J].
BROCHARD, F ;
GENNES, PGD .
JOURNAL DE PHYSIQUE, 1970, 31 (07) :691-&
[9]  
DEGENNES PG, 1993, PHYSICS LIQUID CRYST
[10]   Hard spheres in vesicles: Curvature-induced forces and particle-induced curvature [J].
Dinsmore, AD ;
Wong, DT ;
Nelson, P ;
Yodh, AG .
PHYSICAL REVIEW LETTERS, 1998, 80 (02) :409-412