A Densely and Uniformly Packed Organic Semiconductor Based on Annelated β-Trithiophenes for High-Performance Thin Film Transistors

被引：87

作者：

Tan, Lin ^{[1
]}

Zhang, Lei ^{[1
]}

Jiang, Xi ^{[2
]}

Yang, Xiaodi ^{[1
]}

Wang, Linjun ^{[1
]}

Wang, Zhaohui ^{[1
]}

Li, Liqiang ^{[1
]}

Hu, Wenping ^{[1
]}

Shuai, Zhigang ^{[1
]}

Li, Lin ^{[2
]}

Zhu, Daoben ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Key Lab Organ Solids, Natl Lab Mol Sci, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Inst Chem, Key Lab Polymer Phys & Chem, Beijing 100190, Peoples R China

来源：

ADVANCED FUNCTIONAL MATERIALS | 2009年 / 19卷 / 02期

关键词：

FIELD-EFFECT TRANSISTORS; CROSS-CONJUGATED OLIGOTHIOPHENES; CHARGE-TRANSPORT; ELECTRONIC-STRUCTURE; ASYMMETRIC-SYNTHESIS; MOLECULAR PACKING; N-TYPE; MOBILITY; OLIGOMERS; ULTRAPURE;

D O I：

10.1002/adfm.200800933

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel semiconductor based on annelated beta-trithiophenes is presented, possessing an extraordinary compressed packing mode combining edge-to, face pi-pi interactions and S ... S interactions in single crystals, which is favorable for more effective charge transporting. Accordingly, the device incorporating this semiconductor shows remarkably high charge carrier mobility, as high as 0.89 cm(2) V-1 s(-1), and an on/off ratio of 4.6 x 10(7) for vacuum-deposited thin films.

引用

页码：272 / 276

页数：5

共 54 条

[1] Functionalized pentacene: Improved electronic properties from control of solid-state order [J].

Anthony, JE ;

Brooks, JS ;

Eaton, DL ;

Parkin, SR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (38) :9482-9483

[2]

Bao ZN, 2000, ADV MATER, V12, P227, DOI 10.1002/(SICI)1521-4095(200002)12:3<227::AID-ADMA227>3.0.CO

[3]

2-U

[4] Charge hopping in molecular wires as a sequence of electron-transfer reactions [J].

Berlin, YA ;

Hutchison, GR ;

Rempala, P ;

Ratner, MA ;

Michl, J .

JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (19) :3970-3980

[5] Organic semiconductors:: A theoretical characterization of the basic parameters governing charge transport [J].

Brédas, JL ;

Calbert, JP ;

da Silva, DA ;

Cornil, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2002, 99 (09) :5804-5809

[6] Charge-transfer and energy-transfer processes in π-conjugated oligomers and polymers:: A molecular picture [J].

Brédas, JL ;

Beljonne, D ;

Coropceanu, V ;

Cornil, J .

CHEMICAL REVIEWS, 2004, 104 (11) :4971-5003

[7] Hexathiapentacene: Structure, molecular packing, and thin-film transistors [J].

Briseno, Alejandro L. ;

Miao, Qian ;

Ling, Mang-Mang ;

Reese, Colin ;

Meng, Hong ;

Bao, Zhenan ;

Wudl, Fred .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) :15576-15577

[8] Charge transport in organic semiconductors [J].

Coropceanu, Veaceslav ;

Cornil, Jerome ;

da Silva Filho, Demetrio A. ;

Olivier, Yoann ;

Silbey, Robert ;

Bredas, Jean-Luc .

CHEMICAL REVIEWS, 2007, 107 (04) :926-952

[9] Solid-state packing of conjugated oligomers:: from π-stacks to the herringbone structure [J].

Curtis, MD ;

Cao, J ;

Kampf, JW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (13) :4318-4328

[10] Predictions of hole mobilities in oligoacene organic semiconductors from quantum mechanical calculations [J].

Deng, WQ ;

Goddard, WA .

JOURNAL OF PHYSICAL CHEMISTRY B, 2004, 108 (25) :8614-8621

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