Developments and new applications of UV-induced surface graft polymerizations

被引:395
作者
Deng, Jianping [1 ,2 ]
Wang, Lifu [1 ,2 ]
Liu, Lianying [1 ,2 ]
Yang, Wantai [1 ,2 ]
机构
[1] Beijing Univ Chem Technol, State Key Lab Chem Resource Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
基金
美国国家科学基金会;
关键词
UV light; Polymer surface; Graft polymerization; Modification; Functionalization; CHARGE-TRANSFER COMPLEX; HIGH-DENSITY POLYETHYLENE; CHEMICAL-VAPOR-DEPOSITION; POROUS POLYMER MONOLITHS; HOLLOW-FIBER MEMBRANES; BUTYL VINYL ETHER; POLYETHERKETONE ULTRAFILTRATION MEMBRANE; TRANSFER RADICAL POLYMERIZATION; FOULING SYNTHETIC MEMBRANES; MONOMERS MALEIC-ANHYDRIDE;
D O I
10.1016/j.progpolymsci.2008.06.002
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
As one of the major techniques developed to achieve surface modification of polymeric materials, UV-induced surface graft polymerization has been widely applied as a simple, useful and versatile approach to improve the surface properties of polymers. This review surveys the recent advances in UV light induced surface graft polymerizations, predominantly focusing on: (1) various initiating methods, controlled/living grafting, self-initiated grafting (grafting without the addition of photoinitiators). graft polymerizations with monomer pairs able to form charge transfer (CT) complexes, grafting in liquid, vapor and bulk phase, and the substrates used for grafting; (2) the topography of grafted surface layers, including granular structure, crosslinked structure, and well-defined structure; and (3) the application of techniques to prepare functionalized polymer surfaces with designed performances, e.g., to obtain polymer materials suitable for biomedical applications, membranes or microfluidics. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:156 / 193
页数:38
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