New perspectives for the design of molecular actuators: Thermally induced collapse of single macromolecules from cylindrical brushes to spheres

被引：199

作者：

Li, CM ^{[1
]}

Gunari, N ^{[1
]}

Fischer, K ^{[1
]}

Janshoff, A ^{[1
]}

Schmidt, M ^{[1
]}

机构：

[1] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55128 Mainz, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 09期

关键词：

molecular actuators; nanostructures; polymers; scanning force microscopy;

D O I：

10.1002/anie.200352845

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Polymethacrylates with densely grafted poly-N-isopropylacrylamide side chains change their shape at the lower critical solution temperature from cylindrical brushes (left) to spherical structures (right). This is an interesting example of a temperature-induced cylinder-to-sphere transition observed for single macromolecules.

引用

页码：1101 / 1104

页数：4

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