Ph(2)PNHP(O)Ph(2), a versatile new ligand: Syntheses of monodentate and chelating complexes and a novel Pd2P4N2O2 metallocycle

被引：28

作者：

Smith, MB ^{[1
]}

Slawin, AMZ ^{[1
]}

Woollins, JD ^{[1
]}

机构：

[1] LOUGHBOROUGH UNIV TECHNOL,DEPT CHEM,LOUGHBOROUGH LE11 3TU,LEICS,ENGLAND

来源：

POLYHEDRON | 1996年 / 15卷 / 09期

关键词：

D O I：

10.1016/0277-5387(95)00467-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Oxidation of Ph(2)PNHPPh(2) gave Ph(2)PNHP(O)Ph(2) (1), which reacted with (C3H5)PdCl2Pd(C3H5) to form (C3H5)PdCl(Ph(2)PNHP(O)Ph(2)) (2). Treatment of 2 with Ag[BF4] or Bu(t)OK yielded the almost planar five-membered PdP2NO metallocycle [(C3H5)Pd(Ph(2)PNHP(O)Ph(2))]BF4 (3) or the 'chair'-like 10-membered metallocycle [(C3H5)Pd(Ph(2)PNP(O)Ph(2))(2)Pd(C3H5)] (4) respectively.

引用

页码：1579 / 1583

页数：5

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