Microwave photochemistry.: Photoinitiated radical addition of tetrahydrofuran to perfluorohexylethene under microwave irradiation

被引：60

作者：

Církva, V ^{[1
]}

Hájek, M ^{[1
]}

机构：

[1] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague, Czech Republic

来源：

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY | 1999年 / 123卷 / 1-3期

关键词：

radical addition; microwave irradiation; photoinitiation; electrodeless UV lamp;

D O I：

10.1016/S1010-6030(99)00049-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Generation of UV radiation by microwave field has been applied to a photochemical reaction of perfluorohexylethene with tetrahydrofuran. Reactions were carried out under microwave and UV combined irradiation using a new simple photochemical reactor developed for organic synthetic reactions. Comparative experiments with conventional mercury lamps showed the higher efficiency of microwave electrodeless lamps providing high yield of product in shorter reaction time. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：21 / 23

页数：3

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