Careful scrutiny of the philicity concept

被引：86

作者：

Roy, DR

Parthasarathi, R

Padmanabhan, J

Sarkar, U

Subramanian, V ^{[1
]}

Chattaraj, PK

机构：

[1] Indian Inst Technol, Dept Chem, Kharagpur 721302, W Bengal, India

[2] Cent Leather Res Inst, Chem Lab, Madras 600020, Tamil Nadu, India

来源：

JOURNAL OF PHYSICAL CHEMISTRY A | 2006年 / 110卷 / 03期

关键词：

D O I：

10.1021/jp053641v

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The philicity concept [J. Phys. Chem. A 2003, 107, 4973] is put in proper perspective. In the present work we analyze different physicochemical problems using philicity. It provides satisfactory results in all such cases. We also compare the relative electro(nucleo)philicity with philicity to show that philicity is better than relative electro(nucleo)philicity when the intermolecular reactivity trends are considered and there is hardly any preference of one above the other as far as the intramolecular reactivities are concerned. On the contrary, the philicity concept has some advantages over the other concept.

引用

页码：1084 / 1093

页数：10

共 57 条

[1]

*ACCERLYRS INC, COMMUNICATION

[2] Relationship between local electrophilicity and rate coefficients for the hydrolysis of carbenium ions [J].