Halogen bonding and π•••π stacking control reactivity in the solid state

被引：326

作者：

Caronna, T

Liantonio, R

Logothetis, TA

Metrangolo, P

Pilati, T

Resnati, G

机构：

[1] Politecn Milan, Dept Chem Mat & Chem Engn G Natta, I-20133 Milan, Italy

[2] Univ Milan, CNR, ISTM, Milan, Italy

[3] Univ Bergamo, Fac Engn, I-24044 Bergamo, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 14期

关键词：

D O I：

10.1021/ja039884n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The halogen bonding and the π⋯π stacking interactions induce the noncovalent self-assembly of modules into photoreactive supramolecular architecture. The π⋯π interaction pre-organizes the template, and the halogen bonding aligns the olefins to conform to the topochemical principle for photoreaction. The UV irradiation of the crystal resulted in a cyclization product with quantitative yield and stereospecificity. Copyright © 2004 American Chemical Society.

引用

页码：4500 / 4501

页数：2

共 27 条

[1] Diastereospecific photochemical dimerization of a stilbene-containing daisy chain monomer in solution as well as in the solid state [J].