Generation, entrapment and reactivity of long-lived organic carbocations and radical cations within a supramolecular assembly: Ca Y zeolite

被引：10

作者：

Pitchumani, K

Lakshminarasimhan, PH

Prevost, N

Corbin, DR

Ramamurthy, V

机构：

[1] DUPONT CO INC,CENT RES & DEV,WILMINGTON,DE 19880

[2] TULANE UNIV,DEPT CHEM,NEW ORLEANS,LA 70118

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 02期

关键词：

D O I：

10.1039/a607124d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Diarylethenes spontaneously form the corresponding radical cations and carbocations upon inclusion within activated Ca Y zeolite; oxygen plays an important role in the generation of the radical cations.

引用

页码：181 / 182

页数：2

共 24 条

[1] FORMATION OF RADICAL ION-PAIRS IN ANILINE ADSORPTION ON ZEOLITES [J].

CHEN, FR ;

FRIPIAT, JJ .

JOURNAL OF PHYSICAL CHEMISTRY, 1992, 96 (02) :819-823

[2] ACID ZEOLITES AS ELECTRON ACCEPTORS - USE OF THIANTHRENE RADICAL-CATION AS A PROBE [J].

CORMA, A ;

FORNES, V ;

GARCIA, H ;

MARTI, V ;

MIRANDA, MA .

CHEMISTRY OF MATERIALS, 1995, 7 (11) :2136-2143

[3]

COSTENOBLE ML, 1977, J CHEM SOC F1, V73, P466

[4]

COSTENOBLE ML, 1977, J CHEM SOC F1, V73, P477

[5] HIGH-TEMPERATURE INFRARED SPECTROSCOPY OF PYRIDINE ADSORBED ON FAUJASITES [J].

EBERLY, PE .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (03) :1042-&

[6]

Flanigen E.M., 1991, Introduction to zeolite science and practice, V2nd

[7] SUBSTITUENT-DEPENDENT ELECTRON-TRANSFER-INDUCED PHOTOOXYGENATION OF 1,1-DIARYLETHYLENES [J].

GOLLNICK, K ;

SCHNATTERER, A ;

UTSCHICK, G .

JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (22) :6049-6056

[8] NATURE OF ACID SITES ON CATIONIZED ZEOLITES - CHARACTERIZATION BY INFRARED STUDY OF ADSORBED PYRIDINE AND WATER [J].

HATTORI, H ;

SHIBA, T .

JOURNAL OF CATALYSIS, 1968, 12 (02) :111-&

[9] ELECTRONIC SPECTRA OF OLEFINS ADSORBED ON SILICA-ALUMINA CATALYSTS [J].

LEFTIN, HP ;

HALL, WK .

JOURNAL OF PHYSICAL CHEMISTRY, 1962, 66 (08) :1457-&

[10]

LEFTIN HP, 1960, J PHYS CHEM-US, V64, P382

← 1 2 3 →