A bimodal dithiadiazolyl diradical:: crystal structure and magnetic properties of the 2,2′-dimethylbiphenylene bridged derivative

被引:37
作者
Barclay, TM
Cordes, AW
George, NA
Haddon, RC
Itkis, ME
Oakley, RT [1 ]
机构
[1] Univ Waterloo, Dept Chem, Waterloo, ON N2L 3G1, Canada
[2] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA
[3] Univ Kentucky, Dept Chem, Lexington, KY 40506 USA
[4] Univ Kentucky, Dept Phys, Lexington, KY 40506 USA
[5] Univ Kentucky, Adv Carbon Mat Ctr, Lexington, KY 40506 USA
关键词
D O I
10.1039/a907209h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The two termini of the torsionally strained dithiadiazolyl diradical S2N2C-C6H3Me-MeC6H3-CN2S2 3 possess different solid state structural environments; the bulk magnetic susceptibility of 3 is interpreted in terms of the distinct properties of the two radical centres.
引用
收藏
页码:2269 / 2270
页数:2
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