Synthesis of discrete catalytic oligomers and their potential in silica-supported cooperative catalysis

被引：14

作者：

Chandra, Prakash ^{[1
]}

Jonas, AlainM. ^{[1
]}

Fernandes, Antony E. ^{[1
,2
]}

机构：

[1] Catholic Univ Louvain, Inst Condensed Matter & Nanosci, B-1348 Louvain La Neuve, Belgium

[2] Certech, Rue Jules Bordet, B-7180 Seneffe, Belgium

来源：

RSC ADVANCES | 2019年 / 9卷 / 25期

关键词：

ITERATIVE EXPONENTIAL-GROWTH; AEROBIC OXIDATION; HETEROGENEOUS CATALYSIS; ALCOHOL OXIDATION; FUNCTIONAL-GROUPS; ACID; MECHANISM; DESIGN; AMINE; THIOL;

D O I：

10.1039/c9ra00847k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cooperative catalysis on solid surfaces relies primarily on two or more catalytic partners being close enough to each other to sustain the catalytic cycle. We describe here the synthesis and preliminary investigation of discrete homo-oligomers as flexible scaffolds to inflect the intersite distance and blur the compositional heterogeneity in a silica-grafted catalytic triad.

引用

页码：14194 / 14197

页数：4

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