Selfcondensation of 2-methylpropanal with homochiral BINOL catalysts as a model asymmetric aldol-Tishchenko reaction

被引：28

作者：

Loog, O ^{[1
]}

Mäeorg, U ^{[1
]}

机构：

[1] Tartu State Univ, Inst Organ Chem, EE-51014 Tartu, Estonia

来源：

TETRAHEDRON-ASYMMETRY | 1999年 / 10卷 / 12期

关键词：

D O I：

10.1016/S0957-4166(99)00219-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Binaphtholate catalysts were used to investigate the stereochemistry of 2-methylpropanal selfcondensation, Several steps of this condensation were found to be affected weakly or moderately by homochiral catalysts, but with opposite enantioselectivities. (C) 1999 Elsevier Science Ltd. Al rights reserved.

引用

页码：2411 / 2415

页数：5

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