The nature of the thermodynamically controlled deracemization of 2-benzylcyclohexanone using (R,R)-(-)-trans-2,3-bis(hydroxydiphenylmethyl)-1,4-dioxaspiro[5.4]decane:: a crystallographic result of inclusion complex

被引：16

作者：

Kaku, H ^{[1
]}

Takaoka, S ^{[1
]}

Tsunoda, T ^{[1
]}

机构：

[1] Tokushima Bunri Univ, Fac Pharmaceut Sci, Tokushima 7708514, Japan

来源：

TETRAHEDRON | 2002年 / 58卷 / 17期

关键词：

deracemization; molecular recognition; inclusion; X-ray crystal structures;

D O I：

10.1016/S0040-4020(02)00281-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An X-ray crystallographic study elucidated the structure of the inclusion complex TADDOL 1.(R)-2-benzylcyclohexanone (2). The study disclosed that the assembly of the host molecule I ingeniously includes the guest molecule (R)-2 via hydrogen bonding and van der Waals contacts. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：3401 / 3407

页数：7

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