Concomitant binding of a nickel(II) cation and a nitrate anion by the ligand 2,4,6-tri-2-pyridyl-1,3,5-triazine (TPTZ): The crystal structure of [Ni(HTPTZ)(H2O)(3)](3+)center dot 3NO(3)(-)center dot H2O

被引：44

作者：

Byers, P

Chan, GYS

Drew, MGB

Hudson, MJ

机构：

[1] UNIV READING,DEPT CHEM,READING RG6 2AD,BERKS,ENGLAND

[2] CENFAR,CEA,F-92265 FONTENAY ROSES,FRANCE

来源：

POLYHEDRON | 1996年 / 15卷 / 17期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1016/0277-5387(95)00588-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The structure of the complex [Ni(HTPTZ)(H2O)(3)](3)+. 3NO(3)(-). H2O (TPTZ = 2,4,6-tri-2-pyridyl-1,3,5-triazine) has been investigated. It has been shown that the ligand was tridentate to the nickel cation in the major coordination site and concomitantly was bound to a nitrate anion in the middle coordination site. Analogies have been drawn between the title complex and solvent extraction reagents where nitrate anion is replaced by caprate anion. (C) 1996 Elsevier Science Ltd.

引用

页码：2845 / 2849

页数：5

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