[Ag6(PMo10V2O40)](CH3COO)•8H2O:: A 3D macrocationic polyoxometallic Keggin complex

被引：48

作者：

Liu, FX

Marchal-Roch, C

Bouchard, P

Marrot, J

Simonato, JP

Hervé, G

Sécheresse, F

机构：

[1] Univ Versailles, UMR CNRS 8637, Inst React Electrochim & Microporosites, F-78035 Versailles, France

[2] Rhodia, Ctr Rech Lyon, F-69192 St Fons, France

来源：

INORGANIC CHEMISTRY | 2004年 / 43卷 / 07期

关键词：

D O I：

10.1021/ic035313k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silver atoms and strongly interlinking Keggin units ensure the tridimensionnal macrocationic structure of [Ag-6(PMo10V2O40)](CH3COO).8H(2)O, which catalyzes O-2-based oxidation of p-methoxy-toluene in acetic acid by air.

引用

页码：2240 / 2242

页数：3

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