Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. II. Interplay between electrostatic and gyroscopic interactions

被引：10

作者：

Auzinsh, M. ^{[1
]}

Dashevskaya, E. I. ^{[2
,3
]}

Litvin, I. ^{[3
]}

Nikitin, E. E. ^{[2
,3
]}

Troe, J. ^{[3
,4
]}

机构：

[1] Univ Latvia, Dept Phys, LV-1586 Riga, Latvia

[2] Technion Israel Inst Technol, Schulich Fac Chem, IL-32000 Haifa, Israel

[3] Max Planck Inst Biophys Chem, D-37077 Gottingen, Germany

[4] Univ Gottingen, Inst Phys Chem, D-37077 Gottingen, Germany

来源：

JOURNAL OF CHEMICAL PHYSICS | 2013年 / 139卷 / 14期

关键词：

ADIABATIC CHANNEL MODEL; MUTUAL CAPTURE; METHANE; MOMENT;

D O I：

10.1063/1.4821589

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Within the general axially nonadiabatic channel approach described in Paper I of this series [M. Auzinsh, E. I. Dashevskaya, I. Litvin, E. E. Nikitin, and J. Troe, J. Chem. Phys. 139, 084311 (2013)], the present article analyzes the simultaneous manifestation of electrostatic and gyroscopic interactions in the quantum capture of dipolar polarizable symmetric top molecules by ions. As a demonstration, the rate coefficients for capture of CH3D and CD3H by H+, D+, and H-3(+) are calculated. (C) 2013 AIP Publishing LLC.

引用

收藏

页数：10

相关论文

共 18 条

[1] Quantum capture of charged particles by rapidly rotating symmetric top molecules with small dipole moments: analytical comparison of the fly-wheel and adiabatic channel limits [J].

Auzinsh, M. ;

Dashevskaya, E. I. ;

Nikitin, E. E. ;

Troe, J. .

MOLECULAR PHYSICS, 2013, 111 (14-15) :2003-2011

[2] Quantum effects in the capture of charged particles by dipolar polarizable symmetric top molecules. I. General axially nonadiabatic channel treatment [J].

Auzinsh, M. ;

Dashevskaya, E. I. ;

Litvin, I. ;

Nikitin, E. E. ;

Troe, J. .

JOURNAL OF CHEMICAL PHYSICS, 2013, 139 (08)

[3] Mutual Capture of Dipolar Molecules at Low and Very Low Energies. II. Numerical Study [J].

Auzinsh, M. ;

Dashevskaya, E. I. ;

Litvin, I. ;

Nikitin, E. E. ;

Troe, J. .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (20) :5027-5037

[4] Lambda-doublet specificity in the low-temperature capture of NO(X 2Π1/2) in low rotational states by C+ ions [J].

Auzinsh, M. ;

Dashevskaya, E. I. ;

Litvin, I. ;

Nikitin, E. E. ;

Troe, J. .

JOURNAL OF CHEMICAL PHYSICS, 2009, 130 (01)

[5] DIELECTRIC STUDY OF PARTIALLY ISOTOPE-SUBSTITUTED SOLID AND LIQUID-HYDROGEN AND METHANE [J].

BOHMER, R ;

GIEBENHAIN, U ;

LOIDL, A .

MOLECULAR PHYSICS, 1994, 82 (03) :531-538

[6] Locking of the intrinsic angular momentum in the capture of quadrupole diatoms by ions [J].

Dashevskaya, E. I. ;

Litvin, I. ;

Nikitin, E. E. ;

Troe, J. .

MOLECULAR PHYSICS, 2010, 108 (7-9) :873-882

[7] Axially nonadiabatic channel treatment of low-energy capture in ion-rotating diatom collisions [J].

Dashevskaya, EI ;

Litvin, I ;

Nikitin, EE ;

Oref, I ;

Troe, J .

JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (41) :8703-8712

[8] DIPOLE-MOMENT FUNCTION AND EQUILIBRIUM STRUCTURE OF METHANE IN AN ANALYTICAL, ANHARMONIC 9-DIMENSIONAL POTENTIAL SURFACE RELATED TO EXPERIMENTAL ROTATIONAL-CONSTANTS AND TRANSITION MOMENTS BY QUANTUM MONTE-CARLO CALCULATIONS [J].

HOLLENSTEIN, H ;

MARQUARDT, RR ;

QUACK, M ;

SUHM, MA .

JOURNAL OF CHEMICAL PHYSICS, 1994, 101 (05) :3588-3602

[9]

Landau L. D., 1977, QUANTUM MECH

[10] HYPERFINE ALPHA-DOUBLING SPECTRUM OF N-14O-16 AND N-15O-16 [J].

MEERTS, WL ;

DYMANUS, A .

JOURNAL OF MOLECULAR SPECTROSCOPY, 1972, 44 (02) :320-&