[CuCN•Me3SnCN•C4H4N2]:: A threefold-interpenetrating, distorted-diamondoid framework (C4H3N2 = pyrazine)

被引:54
作者
Siebel, E
Ibrahim, AMA
Fischer, RD
机构
[1] Univ Hamburg, Inst Anorgan & Angew Chem, D-20146 Hamburg, Germany
[2] Ain Shams Univ, Fac Sci, Dept Chem, Cairo, Egypt
关键词
D O I
10.1021/ic9808549
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Notably distorted, adamandoid Cu-10 cages with Cu ... Cu edges of 10.795(6) Angstrom (Cu-CN-Sn(Me-3)-NC-Cu) and 7.142(5) Angstrom (Cu-pyrazine-Cu) are the basic building blocks of the novel supramolecular assembly [CuCN . Me3SnCN . C4H4N2] (C4H4N2 = pyrazine). Interpenetration of three equivalent, distorted-diamondoid frameworks affords comparatively compact crystal packing.
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页码:2530 / +
页数:4
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