Unusual selective substitution of triply bridging carbonyl ligands for GaCp* in Rh6(CO)16.: Synthesis and structural characterization of the Rh6(μ3-CO)4-x(μ3-GaCp*)x(CO)12 clusters, x=1-4

被引：13

作者：

Grachova, EV

Jutzi, P

Neumann, B

Schebaum, LO

Stammler, HG

Tunik, SP

机构：

[1] St Petersburg State Univ, Dept Chem, St Petersburg 198504, Russia

[2] Univ Bielefeld, Fak Chem, D-4800 Bielefeld, Germany

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 03期

关键词：

D O I：

10.1039/b109327d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions of hexanuclear rhodium clusters with GaCp* (Cp* = C5Me5) result in unusual substitution of face bridging CO ligands to give a series of the Rh-6(mu(3)-CO)(4-x) (mu(3)-GaCp*)(x)(CO)(12) substituted derivatives.

引用

页码：302 / 304

页数：3

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