Tetraethylammonium bis(isothiocyanato)-triphenylstannate

被引：11

作者：

Cox, PJ ^{[1
]}

Wardell, JL ^{[1
]}

机构：

[1] UNIV ABERDEEN,DEPT CHEM,ABERDEEN AB9 2UE,SCOTLAND

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195009437

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The [Sn(C6H5)(3)(NCS)(2)](-) organotin anion of the title compound, (C8H20N)[Sn(C6H5)(3)(NCS)(2)], lies on a crystallographic twofold axis and the reigonal bipyramidal structure has NCS groups in axial and phenyl groups in equatorial positions. The tetraethylammonium cation is disordered over two orientations.

引用

收藏

页码：317 / 319

页数：3

相关论文

共 7 条

[1] LIGAND-PAIR FORMATION IN THE PSEUDO-COMPLEX OF 1-(SALICYLIDENEIMINO)-2-METHOXYBENZENE AND TRIPHENYLTIN ISOTHIOCYANATE [J].

CHARLAND, JP ;

GABE, EJ ;

KHOO, LE ;

SMITH, FE .

POLYHEDRON, 1989, 8 (15) :1897-1901

[2] A NITROGEN-GAS-STREAM CRYOSTAT FOR GENERAL X-RAY-DIFFRACTION STUDIES [J].

COSIER, J ;

GLAZER, AM .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1986, 19 (02) :105-107

[3] PENTA-COORDINATED MOLECULES .74. DISTORTION COORDINATE FOR 5-COORDINATED TIN - A MODEL FOR NUCLEOPHILIC-SUBSTITUTION - SYNTHESIS AND STRUCTURE OF HYPERVALENT ANIONIC (CYANOETHYLENEDITHIOLATO)STANNATES [J].

DAY, RO ;

HOLMES, JM ;

SHAFIEEZAD, S ;

CHANDRASEKHAR, V ;

HOLMES, RR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (16) :5377-5383

[4] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES [J].

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 :467-473

[5]

SHELDRICK GM, 1993, SHELXL93 PROGRAM REF

[6] STUDIES IN ARYLTIN CHEMISTRY .8. STRUCTURES OF TETRAETHYLAMMONIUM DIBROMOTRIPHENYL(P-METHYLTHIOPHENYL)STANNATE(N) AND DIBROMOTRIS(P-METHYLTHIOPHENYL)STANNATE(IV) [J].

WHARF, I ;

SIMARD, MG .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 :1605-1609

[7]

ZSOLNAI L, 1994, ZORTEP INTERACTIVE G