The influence of sintering process and atmosphere on the non-ohmic properties of SnO2 based varistor

被引:103
作者
Leite, ER
Nascimento, AM
Bueno, PR
Longo, E
Varela, JA
机构
[1] Univ Fed Sao Carlos, Dept Quim, BR-13560 Sao Carlos, SP, Brazil
[2] Univ Estadual Paulista, Inst Quim, BR-14800 Araraquara, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
D O I
10.1023/A:1008933004042
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
The non-ohmic properties of the 98.95% SnO2 + 1.0 CoO + 0.05 Nb2O5 (all in mole%) system, as well as the influence of sintering temperature and atmosphere on these properties, were characterized in this study. The maximum non-linear coefficient (alpha = 32) was obtained for a sintering temperature of 1300 degrees C in an oxygen atmosphere and this maximum is associated with the presence of O in SnO2 grain boundaries, as interface defects. Experimental results also indicate thermionic-type conduction mechanisms, which are associated with the potential barrier of Schottky or Poole-Frenkel types.
引用
收藏
页码:321 / 327
页数:7
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