Solvent-free synthesis of a microporous metal-organic framework

被引：456

作者：

Pichon, Anne ^{[1
]}

Lazuen-Garay, Ana ^{[1
]}

James, Stuart L. ^{[1
]}

机构：

[1] Queens Univ Belfast, Sch Chem & Chem Engn, Ctr Theory & Appl Catalysis, Belfast BT9 5AG, Antrim, North Ireland

来源：

CRYSTENGCOMM | 2006年 / 8卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b513750k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe the first solvent-free mechanochemical synthesis of a microporous metal-organic framework [Cu(INA)(2)] (INA = isonicotinic acid); the product has robust 3-dimensional connectivity and is obtained quantitatively by grinding together copper acetate and isonicotinic acid for 10 minutes without any applied heating-the high efficiency of the synthesis suggests that mechanochemical synthesis should be further investigated as a convenient method for the preparation of microporous metal-organic frameworks (MOFs).

引用

收藏

页码：211 / 214

页数：4

相关论文

共 30 条

[1] Solvent-free mechanochemical synthesis of two Pt complexes:: cis-(Ph3P)2PtCl2 and cis-(Ph3P)2PtCO3 [J].

Balema, VP ;

Wiench, JW ;

Pruski, M ;

Pecharsky, VK .

CHEMICAL COMMUNICATIONS, 2002, (15) :1606-1607

[2] Channel-containing 1D coordination polymers based on a linear dimetallic spacer [J].

Belcher, WJ ;

Longstaff, CA ;

Neckenig, MR ;

Steed, JW .

CHEMICAL COMMUNICATIONS, 2002, (15) :1602-1603

[3] Mechanochemical and solution reactions between AgCH3COO and [H2NC6H10NH2] yield three isomers of the coordination network {Ag[H2NC6H10NH2]+}∞ [J].

Braga, D ;

Curzi, M ;

Grepioni, F ;

Polito, M .

CHEMICAL COMMUNICATIONS, 2005, (23) :2915-2917

[4] Mechanochemical and solution preparation of the coordination polymers Ag[N(CH2CH2)3N]2[CH3COO]•5H2O and Zn[N(CH2CH2)3N]Cl2 [J].

Braga, D ;

Giaffreda, SL ;

Grepioni, F ;

Polito, M .

CRYSTENGCOMM, 2004, 6 :458-462

[5] Recent advances in solventless organic reactions: towards benign synthesis with remarkable versatility [J].

Cave, GWV ;

Raston, CL ;

Scott, JL .

CHEMICAL COMMUNICATIONS, 2001, (21) :2159-2169

[6]

Chapman ME, 2001, CRYST GROWTH DES, V1, P159, DOI [10.1021/cg005519l, 10.1021/cg0055191]

[7] A chemically functionalizable nanoporous material [Cu3(TMA)2(H2O)3]n [J].

Chui, SSY ;

Lo, SMF ;

Charmant, JPH ;

Orpen, AG ;

Williams, ID .

SCIENCE, 1999, 283 (5405) :1148-1150

[8] Modular chemistry: Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks [J].

Eddaoudi, M ;

Moler, DB ;

Li, HL ;

Chen, BL ;

Reineke, TM ;

O'Keeffe, M ;

Yaghi, OM .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (04) :319-330

[9] Metal-organic frameworks [J].

James, SL .

CHEMICAL SOCIETY REVIEWS, 2003, 32 (05) :276-288

[10] Engineering coordination polymers towards applications [J].

Janiak, C .

DALTON TRANSACTIONS, 2003, (14) :2781-2804