Heterobimetallic iron-platinum phosphino enolate, silyl complexes

被引：8

作者：

Braunstein, P

Stährfeldt, T

Fischer, J

机构：

[1] Univ Strasbourg, UMR CNRS 7513, Chim Coordinat Lab, F-67070 Strasbourg, France

[2] Univ Strasbourg, UMR CNRS 7513, Lab Cristallochim & Chim Struct, F-67070 Strasbourg, France

来源：

COMPTES RENDUS DE L ACADEMIE DES SCIENCES SERIE II FASCICULE C-CHIMIE | 1999年 / 2卷 / 5-6期

关键词：

heterobimetallic complexes; iron-platinum; phosphino enolate ligands; silyl ligands; phosphido ligands; organic isocyanates;

D O I：

10.1016/S1387-1609(00)88535-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In combining the heterobimetallic chemistry of silyl complexes with that of phosphino enolate ligands, we present here the first: heterometallic complexes containing a chelating phosphino enolate ligand and describe the crystal structure of [NMe4] [(OC)(3){(MeO)(3)Si}Fe(mu-PPh2)Pt {Ph2PCH ... C(... O)Ph}] (3e). The presence of the enolato function and the negative charge of complexes 3a-e make them good candidates for reactions with electrophiles and we report preliminary results involving organic isocyanates. (C) Academie des sciences/Elsevier, Paris.

引用

收藏

页码：273 / 282

页数：10

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