Iron corroles and porphyrins as very efficient and highly selective catalysts for the reactions of α-diazo esters with amines

被引：60

作者：

Aviv, I

Gross, Z ^{[1
]}

机构：

[1] Technion Israel Inst Technol, Dept Chem, IL-32000 Haifa, Israel

[2] Technion Israel Inst Technol, Inst Catalysis Sci & Technol, IL-32000 Haifa, Israel

来源：

SYNLETT | 2006年 / 06期

关键词：

diazo compounds; iron; corroles; porphyrins; catalysis;

D O I：

10.1055/s-2006-939035

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iron corroles and porphyrins catalyze the reactions of amines with ethyl diazoacetate extremely efficiently, leading to complete and rapid conversion into N-substituted glycine ethyl esters by simultaneous addition of the Substrates to the catalysts. The selectivity toward activation of the NH bonds is remarkable and quite different from other catalysts.

引用

页码：951 / 953

页数：3

共 30 条

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← 1 2 3 →