Photochemistry of iron(III) complexes

被引：139

作者：

Sima, J

Makanova, J

机构：

来源：

COORDINATION CHEMISTRY REVIEWS | 1997年 / 160卷

关键词：

iron(III) complexes; photochemistry; acacen; dianion of N; N'-ethylenebis(acetylacetoneimine); benacen; N'-ethylenebis(benzoylacetoneimine); bpy, 2,2'-bipyridine; CFC; chlorofluorocarbon; 3-Clpy; 3-chloropyridine; cyt; cytochrome; dcbpy, 4,4'-dicarboxy-2,2'-bipyridine; dib, 1,4-diisocyanobenzene; DMF; N; N-dimethylformamide; DMG; anion of dimethylglyoxime; DMSO; dimethylsulphoxide; edta; tetraanion of ethylenediaminetetraacetic acid; ES; excited state; GS; ground state; HAOX; 2-hydroxyacetophenonoximate anion; HGl; glucose; IL; intraligand; IPCT; ion pair charge transfer; LMCT; ligand-to-metal charge transfer; Mb; myoglobin; MMCT; metal-to-metal charge transfer; NADH; nicotinamide adenine dinucleotide; OEP; dianion of octaethylporphyrin; ox; oxalate dianion; Pc; dianion of phthalocyanine; phen, 1,10-phenanthroline; PPh3; triphenylphosphine; py; pyridine; 15]pyaneN(5), 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo-1(18),14,16-triene; 15]pydieneN(5), 2,13-dimethyl-3,6,9,12,18-pentaazabicyclo[12.3.1]octadeca-1(18),2,12,14,16-pentaene; pyz; pyrazine; RK; anion of kojic acid derivatives; SDS; sodium dodecylsulphate; TDCPP, meso-tetra(2,6-dichlorophenyl)porphyrin; TdPc; dianion of tetrakis(dodecylsulphonamido)phthalocyanine; TLM, 2,3,9,10-tetramethyl-1,4,8,11-tetraazacyclotetradeca-1,3,8,10-tetraene; TMPyP; hexacation of tetrakis(N-methyl-4-pyridion)porphyrin; TPP; dianion of tetraphenylporphyrin; TPPS; hexaanion of tetrakis(4-carboxyphenyl)porphyrin; hexaanion of tetrakis(4-sulphonatophenyl)porphyrin; tz; tetrazine; UroP; decaanion of uroporphyrin;

D O I：

10.1016/S0010-8545(96)01321-5

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this paper, the photochemical properties of ferric complexes are reviewed. The complexes are classified according to the bonding properties of their ligands into classes with unidentate, chelating and macrocyclic ligands. Proteins containing the central atom Fe(III), due to their peculiar properties, are discussed in a separate section. In addition to solution photochemistry, the photoredox processes occurring in microheterogeneous systems, polymer matrices and solid complexes are discussed. In each type of complex the main directions for photochemical research are specified and the current knowledge is evaluated. Practical aspects of the photochemistry of ferric complexes are documented. (C) 1997 Elsevier Science S.A.

引用

页码：161 / 189

页数：29

共 177 条

[1] PHOTOCHEMICAL AND SPECTROSCOPIC STUDIES OF COMPLEXES OF IRON(III) WITH CITRIC-ACID AND OTHER CARBOXYLIC-ACID [J].