Preparation and Characterization of Cellulose Acetate/Aminated Polysulfone Blend Ultrafiltration Membranes and their Application Studies

被引:26
作者
Arockiasamy, D. Lawrence [1 ]
Nagendran, A. [1 ]
Shobana, K. H. [1 ]
Mohan, D. [1 ]
机构
[1] Anna Univ, Membrane Lab, Dept Chem Engn, AC Coll Technol, Madras 600025, Tamil Nadu, India
关键词
Blend membranes; cellulose acetate; metal ion separation; PEG; 600; polyethyleneimine; polysulfone; ultrafiltration; PROTEIN-ADSORPTION-RESISTANCE; HEAVY-METALS; WASTE-WATER; POLYETHERSULFONE MEMBRANES; ACETATE; PERFORMANCE; POLYMER; REMOVAL;
D O I
10.1080/01496390802437297
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ultrafiltration membranes are largely being applied for heavy metal ion separations from aqueous streams. Cellulose acetate (CA) and aminated polysulfone (APSf) based membranes are prepared in the absence and presence of the polymeric additive, polyethylene glycol, PEG 600, in various compositions. The effects of polymer blend composition and additive concentration on compaction, pure water flux, membrane hydraulic resistance, water uptake, and contact angle has been investigated to evaluate the performance of the membranes and the results are discussed. Surface and cross-sectional morphologies of membranes were also analyzed using scanning electron microscopy. Toxic heavy metal ions such as Cu2+, Ni2+, Cd2+, and Zn2+ were separated by the blend membranes using polyethyleneimine (PEI) as polymeric ligand. The rejection and permeate flux efficiencies of the blend membranes are compared with pure cellulose acetate membranes.
引用
收藏
页码:398 / 421
页数:24
相关论文
共 34 条
[1]   Synthesis, characterization and thermal studies on cellulose acetate membranes with additive [J].
Arthanareeswaran, G ;
Thanikaivelan, P ;
Srinivasn, K ;
Mohan, D ;
Rajendran, M .
EUROPEAN POLYMER JOURNAL, 2004, 40 (09) :2153-2159
[2]   Asymmetric polysulfone and polyethersulfone membranes:: effects of thermodynamic conditions during formation on their performance [J].
Barth, C ;
Gonçalves, MC ;
Pires, ATN ;
Roeder, J ;
Wolf, BA .
JOURNAL OF MEMBRANE SCIENCE, 2000, 169 (02) :287-299
[3]   A new pyridine-based 12-membered macrocycle functionalised with different fluorescent subunits;: coordination chemistry towards CuII, ZnII, CdII, HgII, and PbII [J].
Blake, AJ ;
Bencini, A ;
Caltagirone, C ;
De Filippo, G ;
Dolci, LS ;
Garau, A ;
Isaia, F ;
Lippolis, V ;
Mariani, P ;
Prodi, L ;
Montalti, M ;
Zaccheroni, N ;
Wilson, C .
DALTON TRANSACTIONS, 2004, (17) :2771-2779
[4]   NEW MEMBRANES FOR REVERSE-OSMOSIS .1. CHARACTERISTICS OF BASE POLYMER - SULFONATED POLYSULFONES [J].
BROUSSE, C ;
CHAPURLAT, R ;
QUENTIN, JP .
DESALINATION, 1976, 18 (02) :137-153
[5]   Comparison of ion-exchange resins and biosorbents for the removal of heavy metals from plating factory wastewater [J].
Brower, JB ;
Ryan, RL ;
Pazirandeh, M .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1997, 31 (10) :2910-2914
[6]  
CAFLIZARES P, 2002, DESALINATION, V144, P279
[7]   SEM analysis and gas permeability test to characterize polysulfone membrane prepared with polyethylene glycol as additive [J].
Chakrabarty, B. ;
Ghoshal, A. K. ;
Purkait, M. K. .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 320 (01) :245-253
[8]  
CHEN MH, 1996, J APPL POLYM SCI, V32, P793
[9]  
Huheey J. E., 1983, Inorganic Chemistry, V3rd ed.
[10]   Rates of metal electrodeposition from aqueous solutions in the presence of chelating agents [J].
Juang, RS ;
Lin, LC .
SEPARATION SCIENCE AND TECHNOLOGY, 2000, 35 (07) :1087-1098