Nanoscaled polyaniline fibers prepared by ferric chloride as an oxidant

被引：137

作者：

Zhang, LJ

Wan, MX ^{[1
]}

Wei, Y

机构：

[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China

[2] Drexel Univ, Dept Chem, Ctr Adv Polymers & Mat Chem, Philadelphia, PA 19104 USA

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2006年 / 27卷 / 05期

关键词：

ammonium persulfate; ferric hydrochloride; nanofibers; polyaniline; template-free method;

D O I：

10.1002/marc.200500760

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Nanoscaled polyaniline (PANT) fibers with 1730 nm in diameter were successfully prepared by oxidation polymerization using ferric hydrochloride (FeCl3 center dot 6H(2)O) as an oxidant in the presence of p-toluenesulfonic acid (p-TSA), beta-naphthalenesulfonic acid (beta-NSA), and camphorsulfonic acid (CSA) as the dopants. The resulting nanofibers show smaller diameter, higher crystallinity and conductivity (10(-1) S center dot cm(-1)) compared with the nanofibers oxidized by ammonium persulfate (APS), which may be due to the lower oxidation/reduction potential of FeCl3.

引用

页码：366 / 371

页数：6

共 33 条

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[Anonymous], [No title captured]

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