Rhodium/phosphoramidite-catalyzed asymmetric arylation of aldehydes with arylboronic acids

被引:74
作者
Jagt, RBC
Toullec, PY
de Vries, JG
Feringa, BL
Minnaard, AJ
机构
[1] Univ Groningen, Stratingh Inst, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands
[2] DSM Res Life Sci Adv Synth & Catalysis, NL-6160 MD Geleen, Netherlands
关键词
D O I
10.1039/b518311a
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Phosphoramidites are effective chiral ligands in the rhodium catalyzed addition of arylboronic acids to aldehydes providing up to 75% enantioselectivity and up to 96% isolated yield.
引用
收藏
页码:773 / 775
页数:3
相关论文
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