Efficient one-flask synthesis of water-soluble [60]fullerenols

被引：160

作者：

Chiang, LY ^{[1
]}

Bhonsle, JB ^{[1
]}

Wang, LY ^{[1
]}

Shu, SF ^{[1
]}

Chang, TM ^{[1
]}

Hwu, JR ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,ORGANOSILICON & SYNTH LAB,HSINCHU 30043,TAIWAN

来源：

TETRAHEDRON | 1996年 / 52卷 / 14期

关键词：

D O I：

10.1016/0040-4020(96)00104-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-60 molecule exhibited high reactivity towards the addition reaction of nitrogen dioxide radicals (. NO2), which were generated by reaction of sodium nitrite with cone. HNO3. This chemical functionalization of C-60 resulted in polynitro fullerenes, C-60(NO2)(n). Hydrolysis of polynitro fullerenes in aqueous NaOH gave the corresponding polyhydroxylated fullerene derivatives (fullerenols) in moderate overall yields. Results from mass spectra (FAB, negative ion) of fullerenols indicated their structure as C-60 derivatives with at least 16 hydroxy groups. (C) 1996 Elsevier Science Ltd

引用

页码：4963 / 4972

页数：10

共 17 条

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