Copper(I)-catalyzed tandem inter-intramolecular cyclization reactions of zirconacycles: formation of highly substituted styrenes, vinylcyclohexadienes, and related compounds

被引：14

作者：

Xi, ZF

Li, ZP

Umeda, C

Guan, HR

Li, PX

Kotora, M

Takahashi, T ^{[1
]}

机构：

[1] Peking Univ, Hokkaido Univ Joint Lab, Dept Chem, Beijing 100871, Peoples R China

[2] Hokkaido Univ, Grad Sch Pharmaceut Sci, Ctr Catalysis Res, Kita Ku, Sapporo, Hokkaido 0600811, Japan

[3] Japan Sci & Technol Corp, CREST, JST, Kita Ku, Sapporo, Hokkaido 0600811, Japan

来源：

TETRAHEDRON | 2002年 / 58卷 / 06期

基金：

中国国家自然科学基金;

关键词：

vinylated cyclic compounds; five-membered rings; six-membered rings; seven-membered rings; zirconacycles; organocopper compounds; transmetalation; tandem reactions; styrene derivatives;

D O I：

10.1016/S0040-4020(01)01215-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Copper(I)-catalyzed or mediated reactions of five-membered zirconacycles with propargyl or allyl halides afforded a variety of useful vinylated cyclic compounds, including highly substituted styrenes, vinylcyclohexadienes and methylenecycloheptadienes, via tandem inter-intramolecular allylation reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：1107 / 1117

页数：11

共 48 条

[31] FACILE CLEAVAGE OF THE C-BETA-C-BETA'-BOND OF ZIRCONACYCLOPENTENES - CONVENIENT METHOD FOR SELECTIVELY COUPLING ALKYNES WITH ALKYNES, NITRILES, AND ALDEHYDES [J].