The palladium-iminophosphine catalyst for the reactions of organostannanes

被引：50

作者：

Shirakawa, E ^{[1
]}

Hiyama, T

机构：

[1] Japan Adv Inst Sci & Technol, Grad Sch Mat Sci, Tatsunokuchi, Ishikawa 9231292, Japan

[2] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 576卷 / 1-2期

关键词：

cross-coupling; carbostannylation; homocoupling; catalytic cycle; oxidative addition;

D O I：

10.1016/S0022-328X(98)01056-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A palladium complex coordinated by an iminophosphine ligand was found to be a remarkably active catalyst for the coupling of organostannanes with aryl halides. The mechanistic studies show that the reaction of an alkynylstannane proceeds through an unprecedented catalytic cycle which involves an oxidative addition of the organostannane to the Pd(0)-iminophosphine complex. The catalyst was demonstrated to be also useful for the carbostannylation of alkynes and the homocoupling reaction of organostannanes. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：169 / 178

页数：10

共 47 条

[1] Alcaraz L, 1997, SYNLETT, P791
[2] Methyl-, acetyl- and allyl-palladium and -platinum complexes containing the novel chiral phosphorus-imine 2-(diphenylphosphino)benzylidene-S(-)-alpha-methyl-benzylamine ligand
Ankersmit, HA
Loken, BH
Kooijman, H
Spek, AL
Vrieze, K
vanKoten, G
[J]. INORGANICA CHIMICA ACTA, 1996, 252 (1-2) : 141 - 155
[3] [Anonymous], J ORG CHEM
[4] OXIDATIVE ADDITION OF TIN(IV) COMPOUNDS TO ETHYLENE BIS(TRIPHENYLPHOSPHINE)PLATINUM
BUTLER, G
EABORN, C
PIDCOCK, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1979, 181 (01) : 47 - 59
[5] OXIDATIVE ADDITION-REACTIONS OF ORGANOTIN AND ORGANOLEAD COMPOUNDS TO PLATINUM(0) COMPLEX [PT(C2H4)(PPH3)2] - INSERTION OF PLATINUM INTO SN-CL, SN-C, AND PB-C BONDS
BUTLER, G
EABORN, C
PIDCOCK, A
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1978, 144 (02) : C23 - C25
[6] UNSATURATED SIGMA-HYDROCARBYL TRANSITION-METAL COMPLEXES .1. TRIMETHYLTIN ACETYLIDES AS SOURCES OF LATE TRANSITION-METAL DERIVATIVES - METATHESIS, OXIDATIVE ADDITION, AND OXIDATIVE CLEAVAGE
CETINKAYA, B
LAPPERT, MF
MCMEEKING, J
PALMER, DE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (11): : 1202 - 1208
[7] ORGANOPALLADIUM COMPLEXES WITH BIDENTATE PHOSPHORUS AND NITROGEN CONTAINING LIGANDS
DEGRAAF, W
HARDER, S
BOERSMA, J
VANKOTEN, G
KANTERS, JA
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 358 (1-3) : 545 - 562
[8] OXIDATIVE-ADDITION AND REDUCTIVE-ELIMINATION REACTIONS INVOLVING PLATINUM COMPLEXES AND TETRAORGANOTIN COMPOUNDS
EABORN, C
KUNDU, K
PIDCOCK, A
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (05): : 1223 - 1232
[9] OXIDATIVE ADDITION OF TRIORGANOTIN HALIDES TO PLATINUM(O) COMPLEXES
EABORN, C
PIDCOCK, A
STEELE, BR
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1976, (09): : 767 - 776
[10] PALLADIUM-CATALYZED COUPLING OF ARYLSTANNANES WITH ORGANIC SULFONATES - A COMPREHENSIVE STUDY
FARINA, V
KRISHNAN, B
MARSHALL, DR
ROTH, GP
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (20) : 5434 - 5444

← 1 2 3 4 5 →