Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts

被引：1690

作者：

Feng, Dawei ^{[1
]}

Gu, Zhi-Yuan ^{[1
]}

Li, Jian-Rong ^{[1
,2
]}

Jiang, Hai-Long ^{[1
]}

Wei, Zhangwen ^{[1
]}

Zhou, Hong-Cai ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

[2] Beijing Univ Technol, Coll Environm & Energy Engn, Beijing 100124, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2012年 / 51卷 / 41期

关键词：

biomimetic catalyst; mesoporous materials; metal-organic frameworks; oxidation; zirconium; PORPHYRIN; HEME; OXIDATION; ENZYMES; SERIES; CAGES;

D O I：

10.1002/anie.201204475

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Biomimetic MOF: Extremely stable MOFs with different open metal sites and ultra-large 1D channels, PCN-222 (Fe, Mn, Co, Ni, Cu, and Zn), have been assembled with eight-connected Zr6 clusters and redox-active metalloporphyrin motifs. PCN-222(Fe) shows peroxidase-like activity in aqueous solution, exhibiting highly effective biomimetic oxidation on a number of substrates. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：10307 / 10310

页数：4

相关论文

共 50 条

[1] ASSEMBLY OF PORPHYRIN BUILDING-BLOCKS INTO NETWORK STRUCTURES WITH LARGE CHANNELS [J].

ABRAHAMS, BF ;

HOSKINS, BF ;

MICHAIL, DM ;

ROBSON, R .

NATURE, 1994, 369 (6483) :727-729

[2] Zeolite-like metal-organic frameworks as platforms for applications:: On metalloporphyrin-based catalysts [J].

Alkordi, Mohamed H. ;

Liu, Yunling ;

Larsen, Randy W. ;

Eubank, Jarrod F. ;

Eddaoudi, Mohamed .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (38) :12639-+

[3] Metal-adeninate vertices for the construction of an exceptionally porous metal-organic framework [J].

An, Jihyun ;

Farha, Omar K. ;

Hupp, Joseph T. ;

Pohl, Ehmke ;

Yeh, Joanne I. ;

Rosi, Nathaniel L. .

NATURE COMMUNICATIONS, 2012, 3

[4] A Bioinspired Synthetic Approach for Building Metal-Organic Frameworks with Accessible Metal Centers [J].

Barron, Paul M. ;

Wray, Curtis A. ;

Hu, Chunhua ;

Guo, Zhiyong ;

Choe, Wonyoung .

INORGANIC CHEMISTRY, 2010, 49 (22) :10217-10219

[5] Heme-Like Coordination Chemistry Within Nanoporous Molecular Crystals [J].

Bezzu, C. Grazia ;

Helliwell, Madeleine ;

Warren, John E. ;

Allan, David R. ;

McKeown, Neil B. .

SCIENCE, 2010, 327 (5973) :1627-1630

[6] Preparation and kinetic studies of surfactant-horseradish peroxidase ion paired complex in organic media [J].

Bindhu, LV ;

Abraham, TE .

BIOCHEMICAL ENGINEERING JOURNAL, 2003, 15 (01) :47-57

[7] REACTIONS OF HYDROPEROXIDES WITH METALLOTETRAPHENYLPORPHYRINS IN AQUEOUS-SOLUTIONS [J].

BRUICE, TC .

ACCOUNTS OF CHEMICAL RESEARCH, 1991, 24 (08) :243-249

[8] A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability [J].

Cavka, Jasmina Hafizovic ;

Jakobsen, Soren ;

Olsbye, Unni ;

Guillou, Nathalie ;

Lamberti, Carlo ;

Bordiga, Silvia ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (42) :13850-13851

[9] An Interdigitated Metalloporphyrin Framework: Two-Dimensional Tessellation, Framework Flexibility, and Selective Guest Accommodation [J].

Choi, Eun-Young ;

DeVries, Lucas D. ;

Novotny, Richard W. ;

Hu, Chunhua ;

Choe, Wonyoung .

CRYSTAL GROWTH & DESIGN, 2010, 10 (01) :171-176

[10] Highly tunable metal-organic frameworks with open metal centers [J].

Choi, Eun-Young ;

Wray, Curtis A. ;

Hu, Chunhua ;

Choe, Wonyoung .

CRYSTENGCOMM, 2009, 11 (04) :553-555

← 1 2 3 4 5 →