Synthesis of 1,8-bis(cyclam) and 1,8-bis(azacrown) substituted anthracenes by palladium-catalyzed arylation of cyclam

被引：29

作者：

Beletskaya, IP ^{[1
]}

Averin, AD

Bessmertnykh, AG

Denat, F

Guilard, R

机构：

[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119899, Russia

[2] Fac Sci Gabriel, LIMSAG, UMR 5633, F-21100 Dijon, France

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 07期

关键词：

macrocycles; Pd catalysis; aryl halides; amines; amination;

D O I：

10.1016/S0040-4039(01)02356-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Pd-catalyzed arylation of cyclam, cyclen, and azacrown ethers by aryl halides was studied. Cofacial biscyclam and bisazacrown were synthesized by direct bonding of the anthracenyl spacer to a nitrogen atom of macrocycles. (C) Elsevier Science Ltd. All rights reserved.

引用

页码：1193 / 1196

页数：4

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