α-Po nets of copper(II)-trans-1,4-cyclohexanedicarboxylate frameworks based on a paddle-wheel building block and its enlarged dimer

被引：72

作者：

Chen, BL ^{[1
]}

Fronczek, FR

Courtney, BH

Zapata, F

机构：

[1] Univ Texas, Dept Chem, Edinburg, TX 78541 USA

[2] Louisiana State Univ, Dept Chem, Baton Rouge, LA 70803 USA

来源：

CRYSTAL GROWTH & DESIGN | 2006年 / 6卷 / 04期

关键词：

D O I：

10.1021/cg050585e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel three-dimensional frameworks Cu-2(CDC)(2)(4,4'-Bipy)center dot 0.5H(2)CDC center dot 1.25H(2)O (1) and Cu-4(CDC)(4)(4.4'-Bpe) (2) (CDC = trans-1,4-cyclohexanedicarboxylate: 4,4'-Bipy = 4,4'-bipyridine: 4,4'-Bpe = trans-bis(4-pyridyl)ethylene) have been synthesized and structurally rationalized to have doubly interpenetrating elongated primitive cubic (alpha-Po) nets based on a binuclear paddle-wheel motif and its enlarged dimer. respectively. Framework I shows one-dimensional pores filled with trans-1.4-cyclohexanedicarboxylic acids, while framework 2 is a condensed structure because of the enlarged building block.

引用

页码：825 / 828

页数：4

共 38 条

[1] Dinuclear paddle-wheel copper(II) carboxylates in the catalytic oxidation of carboxylic acids. Unusual polymeric chains found in the single-crystal x-ray structures of [tetrakis(mu-1-phenylcyclopropane-1-carboxylato-O,O')bis(ethanol-O)dicopper(II)] and catena-poly[[bis(mu-diphenylacetato-O:O')dicopper](mu(3)-diphenylacetato-1-O:2-O':1'-O')-(mu(3)-diphenylacetato-1-O:2-O':2'-O')]
Agterberg, FPW
Kluit, HAJP
Driessen, WL
Oevering, H
Buijs, W
Lakin, MT
Spek, AL
Reedijk, J
[J]. INORGANIC CHEMISTRY, 1997, 36 (20) : 4321 - 4328
[2] Batten SR, 1998, ANGEW CHEM INT EDIT, V37, P1460, DOI 10.1002/(SICI)1521-3773(19980619)37:11<1460::AID-ANIE1460>3.0.CO
[3] 2-Z
[4] Inorganic crystal engineering using self-assembly of tailored building-blocks
Blake, AJ
Champness, NR
Hubberstey, P
Li, WS
Withersby, MA
Schröder, M
[J]. COORDINATION CHEMISTRY REVIEWS, 1999, 183 : 117 - 138
[5] Carlucci L, 2002, ANGEW CHEM INT EDIT, V41, P1907, DOI 10.1002/1521-3773(20020603)41:11<1907::AID-ANIE1907>3.0.CO
[6] 2-3
[7] A microporous metal-organic framework for gas-chromatographic separation of alkanes
Chen, BL
Liang, CD
Yang, J
Contreras, DS
Clancy, YL
Lobkovsky, EB
Yaghi, OM
Dai, S
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) : 1390 - 1393
[8] Porous Cu-Cd mixed-metal-organic frameworks constructed from Cu(PyaC)2 {Bis[3-(4-pyridyl)pentane-2,4-dionato]copper(II)}
Chen, BL
Fronczek, FR
Maverick, AW
[J]. INORGANIC CHEMISTRY, 2004, 43 (26) : 8209 - 8211
[9] Interwoven metal-organic framework on a periodic minimal surface with extra-large pores
Chen, BL
Eddaoudi, M
Hyde, ST
O'Keeffe, M
Yaghi, OM
[J]. SCIENCE, 2001, 291 (5506) : 1021 - 1023
[10] Cu2(ATC)•6H2O:: Design of open metal sites in porous metal-organic crystals (ATC:1,3,5,7-adamantane tetracarboxylate)
Chen, BL
Eddaoudi, M
Reineke, TM
Kampf, JW
O'Keeffe, M
Yaghi, OM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (46) : 11559 - 11560

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