Determination of standard rate constants for electrochemical irreversible processes from linear sweep voltammograms

被引：213

作者：

Velasco, JG

机构：

[1] Univ. Autónoma de Madrid, Facultad de Ciencias, Cantoblanco, 28049, Madrid

来源：

ELECTROANALYSIS | 1997年 / 9卷 / 11期

关键词：

standard rare constant; irreversible processors;

D O I：

10.1002/elan.1140091116

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new equation has been deduced from which a direct determination of the standard rate constant from linear sweep voltammograms can be made. Some questions related with the detection limit of irreversibility by means of the linear voltammetric method are also discussed.

引用

页码：880 / 882

页数：3

共 10 条

[1] OSCILLOGRAPHIC POLAROGRAPHIC WAVES FOR THE REVERSIBLE DEPOSITION OF METALS ON SOLID ELECTRODES
BERZINS, T
DELAHAY, P
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (03) : 555 - 559
[2] Gokhshtein YP., 1959, DOKL AKAD NAUK SSSR, V126, P598
[3] MATSUDA H, 1955, Z ELEKTROCHEM, V59, P494
[4] SIMPLE ANALYSIS OF QUASI-REVERSIBLE STEADY-STATE VOLTAMMOGRAMS
MIRKIN, MV
BARD, AJ
[J]. ANALYTICAL CHEMISTRY, 1992, 64 (19) : 2293 - 2302
[5] THEORY OF STATIONARY ELECTRODE POLAROGRAPHY - SINGLE SCAN + CYCLIC METHODS APPLIED TO REVERSIBLE IRREVERSIBLE + KINETIC SYSTEMS
NICHOLSON, RS
SHAIN, I
[J]. ANALYTICAL CHEMISTRY, 1964, 36 (04) : 706 - &
[6] RANDLES JEB, 1948, T FARADAY SOC, V44, P327, DOI 10.1039/tf9484400327
[7] NERNST-CONTROLLED CURRENTS IN HANGING-DROP POLAROGRAPHY
REINMUTH, WH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1957, 79 (24) : 6358 - 6360
[8] CYCLIC VOLTAMMETRY WITH ASYMMETRICAL POTENTIAL SCAN - A SIMPLE APPROACH TO MECHANISMS INVOLVING MODERATELY FAST CHEMICAL REACTIONS
SAVEANT, JM
[J]. ELECTROCHIMICA ACTA, 1967, 12 (08) : 999 - &
[9] Sevcik A., 1948, Collect. Czech. Chem. Commun, V13, P349, DOI [10.1135/cccc19480349, DOI 10.1135/CCCC19480349]
[10] Velasco J.G., 1994, ELECTROANAL, V6, P711

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