Tuning of superexchange couplings in a molecule-based ferroferrimagnet: (Ni(II)xMn(II)1-x)(1.5)[Cr-III(CN)(6)]

被引：57

作者：

Ohkoshi, S

Sato, O

Iyoda, T

Fujishima, A

Hashimoto, K

机构：

[1] KANAGAWA ACAD SCI & TECHNOL,ATSUGI,KANAGAWA 24302,JAPAN

[2] UNIV TOKYO,FAC ENGN,DEPT APPL CHEM,BUNKYO KU,TOKYO 113,JAPAN

来源：

INORGANIC CHEMISTRY | 1997年 / 36卷 / 03期

关键词：

D O I：

10.1021/ic960978q

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have succeeded in controlling magnetic properties such as the saturation magnetization, the Weiss temperature and the coercive field using compounds in the series ((NixMn1-xII)-Mn-II)(1.5)[Cr-III(CN)(6)], by the strategy of choosing both ferromagnetic (J > 0) and antiferromagnetic (J < 0) exchange interactions by using the appropriate molar ratios of the transition metal ions. For a composition x = 0.38, the magnetization vs temperature curve exhibited negative magnetization. This type of magnetic behavior can be modeled using molecular field theory with three sublattice (Ni, Mn, Cr) sites.

引用

页码：268 / &

页数：3

共 13 条

[1] A ROOM-TEMPERATURE ORGANOMETALLIC MAGNET BASED ON PRUSSIAN BLUE [J].